1986 Miamisburg train derailment
At 4:25 pm on July 8, 1986, a 44 car Baltimore and Ohio railroad freight train, traveling at 45 miles per hour, bound south to Cincinnati, derailed near Miamisburg, Ohio, a small city with an industrial history in Montgomery County, southwest of Dayton. Fifteen of the cars derailed on a bridge; these were tank cars containing yellow phosphorus, molten sulfur and tallow.
Source: Wikipedia — 1986 Miamisburg train derailment (CC BY-SA 4.0)